Download/Embed scientific diagram | Diagrama de Pourbaix del hierro [12] y voltaje en función del pH (línea azul). from publication: Síntesis de nanopartículas. Download scientific diagram | Diagrama de Pourbaix para especies de cloro considerando una [Cl-] TOT = mM a T = 25°C para la ferrita de manganeso . ESPECIE. ΔG° (cal/mol). Pb. 0. PbO. , Pb3O4. , Pb2O3. , PbO2. , Pb2+. -5, Pb4+. 72, H2O. , REACCIONES DE.

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Using the Nernst equation as above, but with an E 0 of 1. The diagrams are named after Marcel Pourbaix —the Russian -born, Belgian chemist who invented them. The reaction equation is written:. Pourbaix diagrams are also known as E Diagrmaas -pH diagrams due to the labeling of the two axes.

Pourbaix diagram

Retrieved from ” https: Views Read Edit View history. A simplified Pourbaix diagram indicates regions of “Immunity”, “Corrosion” and “Passivity”, instead of the stable species. Piurbaix a function of temperature. Predominant ion boundaries are represented by lines.

The “H” stands for hydrogen, although other standards may be used, and they are for room temperature only. Above this line, water will be oxidized to form oxygen gas, and it will usually not be possible to pass beyond this line as long as there is still water present to be oxidized. The vertical axis is labeled E H for the voltage potential with respect to the standard hydrogen electrode SHE as calculated by the Nernst equation.

For instance, carbonate has a great effect upon the diagram for uranium. By using this site, you agree to the Terms of Use and Privacy Policy. In other projects Wikimedia Commons.


Diagrama de Pourbaix

The reaction equation may be written:. Below this line, water will be reduced to hydrogen, and it will usually not be possible to pass beyond this line as long as there is still water present to be reduced. Passivation occurs when the metal forms a stable coating of an oxide or other salt on its surface, the best example being the relative stability of aluminium because of the diaagramas layer formed on its surface when exposed to air.

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Geological Survey water-Supply Paper Usually, the activity of a species is approximated as equal to the concentration for soluble species or partial pressure for gases. Similarly to phase diagrams, they do not allow for reaction rate or kinetic effects. Archived copy as title Commons category link is on Wikidata. See diagrams at right.

As such a Pourbaix diagram can be read much like a standard phase diagram with a different set of axes. United States Government Pohrbaix Office. The reaction equation is found to be:. Archived from the original on This will vary with temperature. Wikimedia Commons has media related to Pourbaix diagrams.

In addition, changes in temperature and concentration of solvated ions in solution will shift the equilibrium lines in accordance with the Diagrammas equation.

From Wikipedia, the free encyclopedia. Vertical, horizontal, and sloped. The lines in the Pourbaix diagram show the equilibrium conditions, that is, where the activities are equal, for the species on each side of that line.


This page was last edited on 26 Decemberat In order to draw the position of the lines with the Nernst equation, diagrqmas activity of the chemical species at equilibrium must be defined. They thus give a guide to the stability of a particular metal in a specific environment.

The equation must be balanced for M, H, O and charge.

For the simple case of a thermodynamic system consisting of a metal M and water, various reaction equations may be written having the form:. Pourbaix diagrams dlagramas widely used to describe the chemical behaviour of chemical species in the hydrosphere.

Using the expressions for the free energy in terms of potentials, the energy balance is given by a Nernst equation:. There are three types of line boundaries in a Pourbaix diagram: Using the Pourbaix diagram correctly will help shed light not only on the nature of the species present in the solution or sample but may also help to understand the reaction mechanism.

Diagrama de Pourbaix – Wikipedia, la enciclopedia libre

While such diagrams can be drawn for any chemical system, it is important to note that the addition of a metal binding agent ligand will often modify the diagram. Immunity means that the metal is disgramas attacked, while corrosion shows that general attack will occur. The same values should be used for all species present in the system.