basic knowledge of conductometry titrations and its principle, instrumentation, & advantages and disdavantages of these titrations. Conductometry DR. . 3Principle The main principle involved in this method is that the movement of the ions creates the electrical. Conductometry-. Introduction. Ohm’s law. Conductometric measurements. Factor affecting conductivity. Application of conductometry. tometric titration.

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conductoemtry This shows the decrease in the conductivity. This type cell is mainly used for the measurement of the low conductance. The titration of the potassium chloride with the mercuric chlorate. Nehmat Sandhu 10 November at When compared to the acid—base titrations, precipitate titrations are not that much accurate because of the more number of the interferences. Cell constant is defined as the conductivity of the cell: The conductometric apparatus is composed of the following.

After the equivalence point, the addition of the excess of the titrant shows the stability in the conductivity. Used in the determination of the purity of the water. Conductometry is a measurement of electrolytic conductivity to principlee a progress of chemical reaction. Used in the quantitative analysis of the compounds. In usual analytical chemistry practice, the term conductometry is used as a synonym of conductometric titrationwhile the term conductimetry is used to describe non-titrative applications.

Used in the determination of the ionic product of the water. Conductometry free pharmacy study material pharmaceutical analysis pharmaceutical analysis lecture notes.

What are the factors affecting the conductivity measurements? The sample solution is placed on the cell which is conducto,etry of platinum electrodes. This was first proposed by Werner. No need for the specific conductivity.


This contribution in case of a strong acid-strong base is negligible and is not considered there. That is mainly of the number of ions present in the solution.

2. Conductometry – Pharmaceutical Analysis [Book]

The theory is mainly based on Ohm’s law which states that the current I is directly proportional to the electromotive force E and inversely proportional to the resistance R of the conductor: Initially the plot shows the decrease in the conductivity and then shows the increase in the conductivity.

The solutions are compulsory diluted for the measurements. First is the formation of the metal ion and the second one is the formation of the complex. This article needs additional citations for verification.

Journal of Chemical Education,54, Strong acid with strong base curve. All these are operated by the battery. In another case, the titration will form two precipitates. This is because of the ions mobility by increasing the temperature.

Pharmaceutical Analysis by P. D. Chaithanya Sudha

Less satisfactory when compared to other methods. This replacement of the ions with the other ions shows the conductance increase or decrease.

These are commonly employed by dipping in the analyte solution. This continues until the equivalence point is reached, at which one obtains a solution of sodium chloride, NaCl.


Conductomehry acid with weak base: Electroanalysis,22, The princuple point is the point at which the conductivity undergoes a sudden change. Strong acid with weak base: Strong acid with a strong base: Explain the concept of molar conductivity.

Charge of the ions: Please help improve this article by adding citations to reliable sources. Initially the addition of the silver nitrate to the potassium chloride shows the stability in the conductivity and the excess of the silver nitrate addition increases the conductivity because of the formation of the single precipitate.


Hence diluted solutions are cojductometry for the conductivity measurements. The conductance of the sample solution is measured by the resistance measurement by the Wheatstone bridge. The hydrogen ions show sharp decrease in the conductivity.

What is the theory of conductometry? Then the plot between the conductivity and the volume of the titrant shows the plateau. These electrodes are fixed in a constant distance and are sealed in the connected tubes.

Consequently, in the titration of a strong acid with a strong base, the conductance has a minimum at the equivalence point. There are mainly three types of cells conductomery as conductivity cells: Conductometric titration is a type of titration in which the electrolytic conductivity of the reaction mixture is continuously monitored as one reactant is added.

In this method, the primary aromatic amine is reacted with the sodium nitrite in acidic medium to form a diazonium salt. Vorlander first proposed the non-aqueous princople method that is titration of aniline with the HCl in non-aqueous solvent, that is, benzene. For example, magnesium sulphate is titrated with the barium hydroxide and forms two precipitates: In this method, the convuctometry in the hydrogen ions concentration shows the decrease in the conductivity at the end point.